Publications

380. Troshin, K.; Hartwig, J. F. Snap deconvolution: An informatics approach to high-throughput discovery of catalytic reactions. Science 2017357, 175-181.
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379. Jiang, X.; Hartwig, J.F. Iridium-Catalyzed Enantioselective Allylic Substitution of Aliphatic Esters with Silyl Ketene Acetals as the Ester Enolates. Angew. Chem. Int. Ed. 201756, 8887-8891.
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378. Su, B.; Zhou, T.-G.; Xu, P.-L.; Shi, Z.-J.; Hartwig, J. F. Enantioselective Borylation of Aromatic C−H Bonds with Chiral Dinitrogen Ligands. Angew. Chem., Int. Ed. 20170, 7205-7208.
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377. Fier, P.S.; Hartwig, J.F. Site-Selective C-H Fluorination of Pyridines and Diazines with AgF2Org. Synth. 201794, 46-53.
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376. Hartwig, J.F. Catalyst-​Controlled Site-​Selective Bond Activation. Acc. Chem. Res. 201750, 549–555.
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375. Xia, T.; He, L.; Liu, Y.A.; Hartwig, J.F.; Liao, X. Palladium-Catalyzed Cross-Coupling of Ethyl Bromodifluoroacetate with Aryl Bromides or Triflates and Cross-Coupling of Ethyl Bromofluoroacetate with Aryl Iodides. Org. Lett. 201719, 2610-2613.
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374. Lee, T.; Hartwig, J.F. Mechanistic Studies on Rhodium-Catalyzed Enantioselective Silylation of Aryl C–H Bonds. J. Am. Chem. Soc. 2017139, 4879-7886.
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373. Wang, Y.; Bartlett, M.J.; Denard, C.A.; Hartwig, J.F.; Zhao, H. Combining Rh-catalyzed Diazocoupling and Enzymatic Reduction to Efficiently Synthesize Enantioenriched 2-substituted Succinate Derivatives. ACS. Catal. 20177, 2548–2552.
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372. Jin, Y.; Chen, M.; Ge, S.; Hartwig, J.F. Palladium-Catalyzed, Enantioselective α‑Arylation of α‑Fluorooxindoles. Org. Lett. 201719, 1390–1393.
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371. Litman, Z.C.; Sharma, A.; Hartwig, J.F. Oxidation of Hindered Allylic C-h Bonds with Applications to the Functionalization of Complex Molecules. ACS Catal. 20177, 1998-2001.
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370. Key, H.M; Dydio, P.; Liu, Z.; Rha, J.Y-E.; Nazarenko, A.; Seyedkazemi, V.; Clark, D.S.; Hartwig, J.F. Beyond Fe: Iridium-Containing P450 Enzymes for Selective Cyclopropanations of Structurally Diverse AlkenesACS Cent. Sci. 20173, 302-308.
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369. Dydio, P.; Key, H.M.; Hayashi, H.; Clark, D.S.; Hartwig, J.F.  Chemoselective, Enzymatic C-H Bond Amination Catalyzed by a Cytochrome P450 Containing an Ir(Me)-PIX Cofactor. J. Am. Chem. Soc. 2017139, 1750–1753.
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368. Jiang, X.; Beiger, J. J.; Hartwig, J. F. Stereodivergent Allylic Substitutions with Aryl Acetic Acid Esters by Synergistic Iridium and Lewis Base Catalysis. J. Am. Chem. Soc. 2017139, 87–90.
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367. Su, B.; Zhou, T.; Li, X.; Shao, X.; Xu, P.; Wu, W.; Hartwig, J.F.; Shi, Z. A Chiral Nitrogen Ligand for Enantioselective, Iridium-Catalyzed Silylation of Aromatic C-H Bonds. Angew. Chem. Int. Ed.  201756, 1092–1096.
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366. Jiao, Z.; Beiger, J.J.; Jin, Y.; Ge, S.; Zhou, J.; Hartwig, J.F. Palladium-Catalyzed Enantioselective α-Arylation of α-Fluoroketones. J. Am. Chem. Soc. 2016138, 15980–15986.
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365. Lee, S.Y.; Hartwig, J.F. Palladium-​Catalyzed, Site-​Selective Direct Allylation of Aryl C-​H Bonds by Silver-​Mediated C-​H Activation: A Synthetic and Mechanistic Investigation. J. Am. Chem. Soc. 2016138, 15278–15284.
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364. Zhang, J.; Shrestha, R.; Hartwig, J.F.; Zhao, P. A Decarboxylative Approach for Regioselective Hydroarylation of Alkynes. Nature Chem. 20160, ASAP.

363. Karimov, R.R.; Sharma, A.; Hartwig, J.F. Late Stage Azidation of Complex Molecules. ACS Cent. Sci. 20162, 715-724.
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362. Morstein, J.; Kalkman, E.D.; Cheng, C.; Hartwig, J.F. Copper-Mediated C-N Coupling of Arylsilanes with Nitrogen Nucleophiles. Org. Lett. 201618, 5244-5247.
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361. Dydio, P; Key, H.M.; Nazarenko, A.; Rha, J.Y.-E.; Seyedkazemi, V.; Clark, D.S.; Hartwig, J.F. An artificial metalloenzyme with the kinetics of native enzymes. Science 20166308, 102-106.
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360. Gao, F.; Webb, J.D.; Sorek, H.; Wemmer, D.E.; Hartwig, J.F. Fragmentation of Lignin Samples with Commercial Pd/C under Ambient Pressure of Hydrogen. ACS Catal. 20166, 7385-7392.
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359. Cheng, C.; Watts, A.; Hillmyer, M.A.; Hartwig, J.F. Polysilylether: A Degradable Polymer from Biorenewable Feedstocks. Angew. Chem. Int. Ed. 201655, 11872-11876.
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358. Peacock, D.M.; Roos, C.B.; Hartwig, J.F. Palladium-​Catalyzed Cross Coupling of Secondary and Tertiary Alkyl Bromides with a Nitrogen Nucleophile. ACS Cent. Sci. 20162, 647-652.
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357. Chen, M.; Hartwig, J.F. Iridium-​Catalyzed Regio- and Enantioselective Allylic Substitution of Trisubstituted Allylic Electrophiles. Angew. Chem. Int. Ed. 201655, 11651-11655.
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356. Strom, A.E.; Balcells, D.; Hartwig, J.F. Synthetic and Computational Studies on the Rhodium-Catalyzed Hydroamination of Aminoalkenes. ACS. Catal. 20166, 5651-5665.
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355. Zhang, Q.; Brusoe, A.T.; Mascitti, V.; Hesp, K.D.; Blakemore, D.C.; Kohrt, J.T.; Hartwig Fluorodecarboxylation for the synthesis of trifluoromethyl aryl ethers. Angew. Chem. Int. Ed. 201655, 9758-9762.
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354. Lee, T.; Hartwig, J.F. Rhodium-Catalyzed Enantioselective Silylation of Cyclopropyl C-H Bonds. Angew. Chem. Int. Ed. 201655, 8723-8727.
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353. Morstein, J.; Hou, H.; Cheng, C.; Hartwig, J.F. Trifluoromethylation of Arylsilanes with [(phen)CuCF3]. Angew. Chem. Int. Ed. 201655, 8054-8057.
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352. Key, H.M.; Dydio, P.; Clark, D.S.; Hartwig, J.F. Abiological Catalysis by Artificial Heme Proteins Containing Noble Metals in Place of Iron. Nature 2016534, 534-537.
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351. Xi, Y.; Hartwig, J.F. Diverse Asymmetric Hydrofunctionalization of Aliphatic Internal Alkenes through Catalytic Regioselective Hydroboration. J. Am. Chem. Soc. 2016138, 6703-6706.
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350. Hartwig, J.F.; Larsen, M.A. Undirected, Homogeneous C−H Bond Functionalization: Challenges and Opportunities. ACS Cent. Sci. 20162, 281-292.
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349. Jiang, X.; Chen, W.; Hartwig, J.F. Iridium-Catalyzed Diastereoselective and Enantioselective Allylic Substitutions with Acyclic -Alkoxy Ketones. Angew. Chem. Int. Ed. 201655, 5819-5823.
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348. Arlow, S.I.; Hartwig, J.F. Synthesis of Aryldifluoroamides by Copper-​Catalyzed Cross-​Coupling. Angew. Chem. Int. Ed. 201655, 4567-4572.
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347. Larsen, M.A.; Cho, S.H.; Hartwig, J.F. Iridium-Catalyzed, Hydrosilyl-Directed Borylation of Unactivated Alkyl C–H Bonds. J. Am. Chem. Soc. 2016138, 762-765.
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346. Wang, D.Y.; Choliy, Y.; Haibach, M.C.; Hartwig, J.F.; Krogh-Jespersen, K.; Goldman, A.S Assessment of the Electronic Factors Determining the Thermodynamics of "Oxidative Addition" of C–H and N–H Bonds to Ir(I) Complexes. J. Am. Chem. Soc. 2016138, 149-163.
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345. Hartwig, J.F. Evolution of C-H Bond Functionalization from Methane to Methodology. J. Am. Chem. Soc. 2016138, 2-24.
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344. Gao, F.; Webb, J.D.; Hartwig, J.F. Chemo- and Regioselective Hydrogenolysis of Diaryl Ether C−O Bonds by a Robust Heterogeneous Ni/C Catalyst: Applications to the Cleavage of Complex Lignin-Related Fragments. Angew. Chem. Int. Ed. 201655, 1474-1478.
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343. Xi, Y.; Butcher, T.W.; Zhang, J.; Hartwig, J.F. Regioselective, Asymmetric Formal Hydroamination of Unactivated Internal Alkenes. Angew. Chem. Int. Ed. 201655, 776-780.
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342. Madrahimov, S.T.; Li, Q.; Sharma, A.; Hartwig, J.F. Origins of Regioselectivity in Iridium Catalyzed Allylic Substitution. J. Am. Chem. Soc. 2015137, 14968-14981.
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341. Chen, M.; Hartwig, J.F. Iridium-Catalyzed Enantioselective Allylic Substitution of Enol Silanes from Vinylogous Esters and Amides. J. Am. Chem. Soc. 2015137, 13972-13979.
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340. Schramm, Y.; Takeuchi, M.; Semba, K.; Nakao, Y.; Hartwig, J.F. Anti-Markovnikov Hydroheteroarylation of Unactivated Alkenes with Indoles, Pyrroles, Benzofurans, and Furans Catalyzed by a Nickel–N-Heterocyclic Carbene System. J. Am. Chem. Soc. 2015137, 12215–12218.
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339. Larsen, M.A.; Wilson, C.V.; Hartwig, J.F. Iridium-Catalyzed Borylation of Primary Benzylic C–H Bonds without a Directing Group: Scope, Mechanism, and Origins of Selectivity. J. Am. Chem. Soc. 2015137, 8633-8643.
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338. Brusoe, A.T.; Hartwig, J.F. Palladium-Catalyzed Arylation of Fluoroalkylamines. J. Am. Chem. Soc. 2015137, 8460–8468.
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337. Cheng, C.; Hartwig, J.F. Catalytic Silylation of Unactivated C−H Bonds. Chem. Rev. 2015115, 8946-8975.

336. Key, H.M.; Clark, D.S.; Hartwig, J.F. Generation, Characterization, and Tunable Reactivity of Organometallic Fragments Bound to a Protein Ligand. J. Am. Chem. Soc. 2015137, 8261-8268.
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335. Lee, T.; Wilson, T.W.; Berg, R.; Ryberg, P.; Hartwig, J.F. Rhodium-Catalyzed Enantioselective Silylation of Arene C-H bonds: Desymmetrization of Diarylmethanols. J. Am. Chem. Soc. 2015137, 6742-6745.
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334. Denard, C.A.; Bartlett, M.J.; Wang, J.; Lu, L.; Hartwig, J.F.; Zhao, H. Development of a one-pot tandem reaction combining ruthenium-catalyzed alkene metathesis and enantioselective enzymatic oxidation to produce aryl epoxides. ACS Catal. 20155, 3817-3822.
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333. Cheng, C.; Hartwig, J.F. Iridium-Catalyzed Silylation of Aryl C−H Bonds. J. Am. Chem. Soc. 2015137, 592-595.
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332. Green, R.A.; Hartwig, J.F. Nickel-Catalyzed Amination of Aryl Chlorides with Ammonia or Ammonium Salts. Angew. Chem. Int. Ed. 201554, 3768-3772.
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331. Sharma, A.; Hartwig, J.H. Metal-Catalyzed Azidation of Tertiary C–H Bonds Suitable for Late-Stage Functionalization. Nature 2015517, 600-604.

330. Tran, B. L.; Driess, M.; Hartwig, J. F. Copper-Catalyzed Oxidative Dehydrogenative Carboxylation of Unactivated Alkanes to Allylic Esters via Alkenes. J. Am. Chem. Soc. 2014136, 17292-17301.
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329. Ge, S.; Arlow, S.I.; Mormino, M.G.; Hartwig, J.F. Pd-Catalyzed α‑Arylation of Trimethylsilyl Enolates of α,α-Difluoroacetamides. J. Am. Chem. Soc. 2014136, 14401-14404.
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328. Chen, W.; Chen, M.; Hartwig, J.F. Diastereo- and Enantioselective Iridium-Catalyzed Allylation of Cyclic Ketone Enolates: Synergetic Effect of Ligands and Barium Enolates. J. Am. Chem. Soc. 2014136, 15825-15828.
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327. Bair, J.S.; Schramm, Y.; Sergeev, A.G.; Clot, E.; Eisenstein, O.; Hartwig, J.F. Linear-Selective Hydroarylation of Unactivated Terminal and Internal Olefins with Trifluoromethyl-Substituted Arenes. J. Am. Chem. Soc. 2014136, 13098-13101.
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326. Chen, M.; Hartwig, J.F. Iridium-Catalyzed Regio- and Enantioselective Allylic Substitution of Silyl Dienolates Derived from Dioxinones. Angew. Chem. Int. Ed. 201453, 1-6.
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325. Cheng, C.; Hartwig, J.F. Mechanism of the Rhodium-Catalyzed Silylation of Arene C−H Bonds. J. Am. Chem. Soc. 2014136, 12064-12072.
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324. Sevov, C.S.; Hartwig, J.F. Iridium-Catalyzed Oxidative Olefination of Furans with Unactivated Alkenes. J. Am. Chem. Soc. 2014136, 10625-10631.
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323. Fier, P.S.; Hartwig, J.F. Synthesis and Late-Stage Functionalization of Complex Molecules through C−H Fluorination and Nucleophilic Aromatic Substitution. J. Am. Chem. Soc. 2014136, 10139-10147.
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322. Green, R.A.; Hartwig, J.F. Palladium-Catalyzed Amination of Aryl Chlorides and Bromides with Ammonium Salts. Org. Lett. 201416, 4388−4391.
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321. Li, B.; Driess, M.; Hartwig, J.F. Iridium-Catalyzed Regioselective Silylation of Secondary Alkyl C−H Bonds for the Synthesis of 1,3-Diols. J. Am. Chem. Soc. 2014136, 6586-6589.
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320. Li, Q.; Driess, M.; Hartwig, J.F. Iridium-Catalyzed Regioselective Silylation of Aromatic and Benzylic C-H Bonds Directed by a Secondary Amine. Angew. Chem. Int. Ed. 201453, 1-5.
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319. Li, Q.; Liskey, C.W.; Hartwig, J.F. Regioselective Borylation of the C–H Bonds in Alkylamines and Alkyl Ethers. Observation and Origin of High Reactivity of Primary C–H Bonds Beta to Nitrogen and Oxygen. J. Am. Chem. Soc. 2014136, 8755–8765.
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318. Chen, M.; Hartwig, J.F. Iridium-Catalyzed Enantioselective Allylic Substitution of Unstabilized Enolates Derived from α,β-Unsaturated Ketones. Angew. Chem. Int. Ed. 201453, 1-6.
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317. Mormino, M.G.; Fier, P.S.; Hartwig, J.F. Copper-Mediated Perfluoroalkylation of Heteroaryl Bromides with (phen)CuRF. Org. Lett. 201416, 1744-1747.
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316. Cho, S.H.; Hartwig, J.F. Iridium-catalyzed diborylation of benzylic C–H bonds directed by a hydrosilyl group: synthesis of 1,1-benzyldiboronate esters. Chem. Sci. 20145, 694-698.

315. Larsen, M.A.; Hartwig, J.F. Iridium-Catalyzed C−H Borylation of Heteroarenes: Scope, Regioselectivity, Application to Late-Stage Functionalization, and Mechanism. J. Am. Chem. Soc. 2014136, 4287-4299.
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314. Ge, S.; Chaładaj, W.; Hartwig, J.F. Pd-Catalyzed α‐Arylation of α,α-Difluoroketones with Aryl Bromides and Chlorides. A Route to Difluoromethylarenes. J. Am. Chem. Soc. 2014136, 4149-4152.
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313. Cheng, C.; Hartwig, J.F. Rhodium-Catalyzed Intermolecular C–H Silylation of Arenes with High Steric Regiocontrol. Science. 2014343, 853-857.

312. Sevov, C.S; Zhou, J. (Steve); Hartwig, J.H. Iridium-Catalyzed, Intermolecular Hydroamination of Unactivated Alkenes with Indoles. J. Am. Chem. Soc. 2014136, 3200-3207.
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311. Tran, B.L.; Li, B.; Driess, M.; Hartwig, J.F. Copper-Catalyzed Intermolecular Amidation and Imidation of Unactivated Alkanes. J. Am. Chem. Soc. 2014136, 2555-2563.
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310. Ge. S.; Green, R.A.; Hartwig, J.F. Controlling First-Row Catalysts: Amination of Aryl and Heteroaryl Chlorides and Bromides with Primary Aliphatic Amines Catalyzed by a BINAP-Ligated Single-Component Ni(0) Complex. J. Am. Chem. Soc. 2014136, 1617-1627.
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309. Chen, W.; Hartwig, J.F. Cation Control of Diastereoselectivity in Iridium-Catalyzed Allylic Substitutions. Formation of Enantioenriched Tertiary Alcohols and Thioethers by Allylation of 5H-Oxazol-4-ones and 5H-Thiazol-4-ones. J. Am. Chem. Soc. 2014136, 377-382.
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308. Denard, C.A.; Huang, H.; Bartlett, M.J.; Lu, L.; Tan, Y.; Zhao, H.; Hartwig, J.F. Cooperative Tandem Catalysis by an Organometallic Complex and a Metalloenzyme. Angew. Chem. Int. Ed. 201453, 465-469.
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307. Hama, T.; Ge, S.; Hartwig, J.F. Palladium-Catalyzed α-Arylation of Zinc Enolates of Esters: Reaction Conditions and Substrate Scope. J. Org. Chem. 201378, 8250-8266.
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306. Denard, C.A.; Hartwig, J.F.; Zhao, H. Multistep One-Pot Reactions Combining Biocatalysts and Chemical Catalysts for Asymmetric Synthesis. ACS Catal. 20133, 2856-2864.
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305. Fier, P.S.; Hartwig, J.F. Selective C-H Fluorination of Pyridines and Diazines Inspired by a Classic Amination Reaction. Science 2013342, 956-960.

304. Sharma, A.; Hartwig, J.F. Enantioselective Functionalization of Allylic C–H Bonds Following a Strategy of Functionalization and Diversification. J. Am. Chem. Soc. 2013135, 17983-17989.
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303. Gallego, D.; Brück, A.; Irran, E.; Meier, F.; Kaupp, M.; Driess, M.; Hartwig, J.F. From Bis(silylene) and Bis(germylene) Pincer-Type Nickel(II) Complexes to Isolable Intermediates of the Nickel-Catalyzed Sonogashira Cross-Coupling Reaction. J. Am. Chem. Soc. 2013135, 15617-15626.
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302. Hanley, P.S.; Hartwig, J.H. Migratory Insertion of Alkenes into Metal–Oxygen and Metal–Nitrogen Bonds. Angew. Chem. Int. Ed.  201352, 8510-8525.
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301. Strom, A.E.; Hartwig, J.H. One-Pot Anti-Markovnikov Hydroamination of Unactivated Alkenes by Hydrozirconation and Amination. J. Org. Chem. 201378, 8909-8914.
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300. Cheng, C.; Simmons, E.M.; Hartwig, J.H. Iridium-Catalyzed, Diastereoselective Dehydrogenative Silylation of Terminal Alkenes with (TMSO)2MeSiH. Angew. Chem. Int. Ed. 201352, 8984 –8989.
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299. Liskey, C.W.; Hartwig, J.F. Borylation of Arenes with Bis(hexylene glycolato)diboron. Synthesis 201345, 1837–1842.

298. Sevov, C.S.; Hartwig, J.F. Iridium-Catalyzed, Intermolecular Hydroetherification of Unactivated Aliphatic Alkenes with Phenols. J. Am. Chem. Soc. 2013135, 9303–9306.
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297. Shrestha, R.; Mukherjee, P.; Tan, Y.; Litman, Z.C.; Hartwig, J.F. Sterically Controlled, Palladium-Catalyzed Intermolecular Amination of Arenes. J. Am. Chem. Soc. 2013135, 8480-8483.
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296. Cho, S.H.; Hartwig, J.F. Iridium-Catalyzed Borylation of Secondary Benzylic C–H Bonds Directed by a Hydrosilane. J. Am. Chem. Soc. 2013135, 8157–8160.
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295. Liskey, C.W.; Hartwig, J.F. Iridium-Catalyzed C–H Borylation of Cyclopropanes. J. Am. Chem. Soc. 2013135, 3375–3378.
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294. Chen, W.; Hartwig, J.F. Control of Diastereoselectivity for Iridium-Catalyzed Allylation of a Prochiral Nucleophile with a Phosphate Counterion. J. Am. Chem. Soc. 2013135, 2068−2071.
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293. Sevov, C.S.; Hartwig, J.F. Iridium-Catalyzed Intermolecular Asymmetric Hydroheteroarylation of Bicycloalkenes. J. Am. Chem. Soc. 2013135, 2116−2119.
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292. Fier, P.S.; Luo, J.; Hartwig, J.F. Copper-Mediated Fluorination of Arylboronate Esters. Identification of a Copper(III) Fluoride Complex. J. Am. Chem. Soc. 2013135, 2552−2559.
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291. Robbins, D.W.; Hartwig, J.F. Sterically Controlled Alkylation of Arenes through Iridium-Catalyzed C-H Borylation. Angew. Chem. Int. Ed. 201352, 933–937.
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290. Partridge, B.M.; Hartwig, J.F. Sterically Controlled Iodination of Arenes via Iridium-Catalyzed C-H Borylation. Org. Lett. 201315, 140–143.
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289. Fier, P.S.; Hartwig, J.F. Synthesis of Difluoromethyl Ethers with Difluoromethyltriflate. Angew. Chem. Int. Ed. 201352, 1–5.
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288. Ge, S.; Hartwig, J.F. Highly Reactive, Single-Component Nickel Catalyst Precursor for Suzuki-Miyuara Cross-Coupling of Heteroaryl Boronic Acids with Heteroaryl Halides. Angew. Chem. Int. Ed. 201251, 12837–12841.
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287. Bruck, A.; Gallego, D.; Wang, W. Y.; Irran, E.; Driess, M.; Hartwig, J. F. Pushing the σ-Donor Strength in Iridium Pincer Complexes: Bis(silylene) and Bis(germylene) Ligands Are Stronger Donors than Bis(phosphorus(III)) Ligands. Angew. Chem. Int. Ed. 201251, 11478–11482.
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286. Sergeev, A.G.; Webb, J.D.; Hartwig, J.F. A Heterogeneous Nickel Catalyst for the Hydrogenolysis of Aryl Ethers without Arene Hydrogenation. J. Am. Chem. Soc. 2012134, 20226–20229.
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285. Chen, C.; Weng, Z.; Hartwig, J.F. Synthesis of Copper(I) Thiolate Complexes in the Thioetherification of Aryl Halides. Organometallics 201231, 8031–8036.
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284. Chen, W.; Hartwig, J.F. Iridium-Catalyzed Regioselective and Enantioselective Allylation of Trimethylsiloxyfuran. J. Am. Chem. Soc. 2012134, 15249–15252.
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283. Litvinas, N.D.; Fier, P.S.; Hartwig, J.F. A General Strategy for the Perfluoroalkylation of Arenes and Arylbromides by Using Arylboronate Esters and [(phen)CuRF. Angew. Chem. Int. Ed. 201251, 536-539.
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282. Hanley, P.S.; Marquard, S.L.; Cundari, T.R.; Hartwig, J.F. Reductive Elimination of Alkylamines from Low-Valent, Alkylpalladium(II) Amido Complexes. J. Am. Chem. Soc. 2012134, 15281–15284.
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281. Robbins, D.W.; Hartwig, J.F. A C-H Borylation Approach to Suzuki-Miyaura Coupling of Typically Unstable 2-Heteroaryl and Polyfluorophenyl Boronates. Org. Lett. 201214, 4266–4269.
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280. Liskey, C.W.; Hartwig, J.F. Iridium-Catalyzed Borylation of Secondary C-H Bonds in Cyclic Ethers. J. Am. Chem. Soc. 2012134, 12422–12425.
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279. Sevov, C.S.; Zhou, J.; Hartwig, J.F. Iridium-Catalyzed Intermolecular Hydroamination of Unactivated Aliphatic Alkenes with Amides and Sulfonamides. J. Am. Chem. Soc. 2012134, 11960–11963.
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278. Fier, P.S.; Hartwig, J.F. Copper Mediated Difluoromethylation of Aryl and Vinyl Iodides. J. Am. Chem. Soc. 2012134, 5524–5527.
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277. Fier, P.S.; Hartwig, J.F. Copper-Mediated Fluorination of Aryl Iodides. J. Am. Chem. Soc. 2012134, 10795-10798.
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276. Hartwig, J.F. Borylation and Silylation of C–H Bonds: A Platform for Diverse C–H Bond Functionalizations. Acc. Chem. Res.  201245, 864–873.
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275. Klinkenberg, J.L.; Hartwig, J.F. Reductive Elimination from Arylpalladium Cyanide Complexes. J. Am. Chem. Soc.  2012134, 5758–5761.
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274. Simmons, E.M.; Hartwig, J.F. Catalytic functionalization of unactivated primary C–H bonds directed by an alcohol. Nature 2012483, 70–73.

273. Tan, Y.; Barrios-Landeros, F; Hartwig, J.F. Mechanistic Studies on Direct Arylation of Pyridine N-Oxide: Evidence for Cooperative Catalysis between Two Distinct Palladium Centers. J. Am. Chem. Soc.  2012134, 3683–3686.
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272. Huang, Z.; Hartwig, J.F. Copper(I) Enolate Complexes in Alpha-Arylation Reactions: Synthesis, Reactivity, and Mechanism. Angew. Chem. Int. Ed.  201251, 1028–1032.
TOC

271. Shen, Q.; Guo, F.; Hartwig, J.F. Aryl- and Hetarylamines with Hetaryl Electrophiles. In Cross Coupling and Heck-Type Reactions 2; Wolfe, J.P., Ed.; Georg Thieme Verlag K: Stuttgart, Germany, 2012; pp 173-194.

270. Morimoto, H.; Tsubogo, T.; Litvinas, N.D.; Hartwig, J.F. A Broadly Applicable Copper Reagent for Trifluoromethylations and Perfluoroalkylations of Aryl Iodides and Bromides. Angew. Chem. Int. Ed.  201150, 3793–3798.
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269.  Hartwig, J.F. Regioselectivity of the borylation of alkanes and arenes. Chem. Soc. Rev.  201140, 1992–2002.

268.  Sergeev, A.G.; Hartwig, J.F. Selective, Nickel-Catalyzed Hydrogenolysis of Aryl Ethers. Science  2011332, 439–443.

267.  Marquard, S.L.; Hartwig, J.F C(sp3)–O Bond-Forming Reductive Elimination of Ethers from Bisphosphine-Ligated Benzylpalladium(II) Aryloxide Complexes. Angew. Chem. Int. Ed.  201150, 7119–7123.
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266.  Hanley, P.S.; Hartwig, J.F.  Intermolecular Migratory Insertion of Unactivated Olefins into Palladium–Nitrogen Bonds. Steric and Electronic Effects on the Rate of Migratory Insertion. J. Am. Chem. Soc.  2011133, 15661-15673.
TOC

265.  Ge, S.; Hartwig, J.F. Nickel-catalyzed Asymmetric α-Arylation and Heteroarylation of Ketones with Chloroarenes: Effect of Halide on Selectivity, Oxidation State and Room Temperature Reactions. J. Am. Chem. Soc 2011133, 16330-16333.
TOC

264.  Robbins, D.W.; Hartwig, J.F. A Simple, Multi-Dimensional Approach to High-Throughput Discovery of Catalytic Reactions. Science 2011333, 1423-1427.

263. Zhijian Liu, Z.; Yamamichi, H.; Madrahimov, S.T.; Hartwig, J.F. Rhodium Phosphine-π-Arene Intermediates in the Hydroamination of Alkenes. J. Am. Chem. Soc 2011133, 2772-2782.
TOC

262. Tan, Y.; Hartwig, J. F. Assessment of the Intermediacy of Arylpalladium Carboxylate Complexes in the Direct Arylation of Benzene: Evidence for C-H Bond Cleavage by ‘Ligandless’ Species. J. Am. Chem. Soc 2011133, 3308-3311.
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261. Carrow, B. P.; Hartwig, J. F. Distinguishing Between Pathways for Transmetalation in Suzuki-Miyaura Reactions. J. Am. Chem. Soc 2011133, 2116-2119.
TOC

260. Huang, D.S.; DeLuca, R. J.; Hartwig, J.F. α-Arylation of Esters Catalyzed by the Pd(I) Dimer [P(t-Bu)3]Pd(m-Br)]2Org. Synth. 201188, 4-13.

259. Liao, X.; Stanley, L.M.; Hartwig, J.F. Enantioselective Total Syntheses of (−)-Taiwaniaquinone H and (−)-Taiwaniaquinol B by Iridium-Catalyzed Borylation and Palladium-Catalyzed Asymmetric α-Arylation. J. Am. Chem. Soc.  2011133, 2088-2091.
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258. Hartwig, J.F. Hydrocarbon Synthesis: Ringing The Chains. Nature Chemistry 20113, 99-101.

257. Klinkenberg, J.L.; Hartwig, J.F. Catalytic Organometallic Reactions of Ammonia. Angew. Chem. Int. Ed.  201150, 86-95.
TOC

256. Hartwig, J.F.; Pouy, M.J. Iridium-Catalyzed Allylic Substitution. In Iridium Catalysis; Andersson, P. G., Ed.; Springer-Verlag: Berlin, Germany, 2011; pp 169-208.

255. Julian, J.D.; Hartwig, J.F. Intramolecular Hydroamination of Unbiased and Functionalized Primary Aminoalkenes Catalyzed by a Rhodium Aminophosphine Complex. J. Am. Chem. Soc.  2010132, 13813-13822.
TOC

254.  Giri, R.: Hartwig, J.F. Cu(I) Amido Complexes in the Ullmann Reaction. Reactions of Cu(I)-Amido Complexes with Iodoarenes with and without Autocatalysis by CuI. J. Am. Chem. Soc.  2010132, 15860-15863.
TOC

253. Simmons, E.M.; Hartwig, J.F. Iridium-Catalyzed Arene ortho-Silylation by Formal Hydroxyl-Directed C-H Activation. J. Am. Chem. Soc.  2010132, 17092-17095.
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252.  Stanley, L.M.; Hartwig, J.F. Mechanistically Driven Development of Iridium Catalysts for Asymmetric Allylic Substitution. Acc. Chem. Res. 201043, 1461-1475.
TOC

251.  Huang, D.S.; Hartwig, J.F. Palladium-Catalyzed γ-Arylation of α,β-Unsaturated Esters from Silyl Ketene Acetals. Angew. Chem. Int. Ed.  201049, 5757-5761 (designated as a "Hot Paper").
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250. Klinkenberg, J.L.; Hartwig, J.F. Slow Reductive Elimination from Arylpalladium Parent Amido Complexes. J. Am. Chem. Soc.  2010132, 11830-11833.
TOC

249. Liskey, C.W.; Xuebin Liao, X.; Hartwig, J.F. Cyanation of Arenes via Iridium-Catalyzed Borylation. J. Am. Chem. Soc.  2010132, 11389-11391.
TOC

248. Huang, Z.; Zhou, J. Hartwig, J.F. N-H Activation of Hydrazines by Iridium(I). Double N-H Activation to Form Iridium Aminonitrene Complexes. J. Am. Chem. Soc.  2010132, 11458-11460.
TOC

247. Stanley, L. M.; Bai, C.; Ueda, M.; Hartwig, J. F. Iridium-Catalyzed Kinetic Asymmetric Transformations of Racemic Allylic Benzoates. J. Am. Chem. Soc.  2010132, 8918-8920.
TOC

246. Fernandez-Rodriguez, M.A.; Hartwig, J.F. One-Pot Synthesis of Unsymmetrical Diaryl Thioethers by Palladium-Catalyzed Coupling of Two Aryl Bromides and a Thiol Surrogate. Chem.—Eur. J. 201016, 2355-2359.
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245. Hanley, P.S.; Markovic, D.; Hartwig, J.F. Intermolecular Insertion of Ethylene and Octene into a Palladium-Amide Bond. Spectroscopic Evidence for an Ethylene Amido Intermediate. J. Am. Chem. Soc. 2010132, 6302-6303.
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244. Robbins, D.W.; Boebel, T. A.; Hartwig, J.F. Iridium-Catalyzed, Silyl-Directed Borylation of Nitrogen-Containing Heterocycles. J. Am. Chem. Soc.  2010132, 4068-4069.
TOC

243. Tan, Y.; Hartwig, J.F. Palladium-Catalyzed Amination of Aromatic C–H Bonds with Oxime Esters. J. Am. Chem. Soc.  2010132, 3676-3677.
TOC

242. Tye, J.W.; Weng, Z.; Giri, R.; Hartwig J.F. Copper(I) Phenoxide Complexes in the Etherification of Aryl Halides. Angew. Chem. Int. Ed.  201049, 2185-2189.
TOC

241. Sawyer, K.R., Cahoon, J.F., Shanoski, J.E., Glascoe, E.A., Kling, M.F., Schlegel, J.P., Zoerb, M.C., Hapke, M., Hartwig, J.F., Webster, C.E., Harris, C.B. Time-resolved IR Studies on the Mechanism for the Functionalization of Primary C−H Bonds by Photoactivated Cp*W(CO)3(Bpin). J. Am. Chem. Soc. 2010132, 1848-1859.
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240. Wei, C.S.; Jiménez-Hoyos, C.A.; Videa, M.F.; Hartwig, J.F.; Hall, M.B. Origins of the Selectivity for Borylation of Primary over Secondary C–H Bonds Catalyzed by Cp*-Rhodium Complexes. J. Am. Chem. Soc. 2010132, 3078-3091.
TOC

239.  Marquard, S.L.; Rosenfeld, D.C.; Hartwig, J.F. C(sp3)-N Bond-Forming Reductive Elimination of Amines: Reactions of Bisphosphine-Ligated Benzylpalladium(II) Diarylamido Complexes. Angew. Chem. Int. Ed. 201049, 793.

238. Mkhalid, I.A.I.; Barnard, J.H.; Marder, T.B.; Murphy, J.M.; Hartwig, J.F. C-H Activation for the Construction of C-B Bonds. Chem. Rev. 2010110, 890-931.

236. Carrow, B.P.; Hartwig, J.F. Ligandless, Anionic, Arylpalladium Halide Intermediates in the Heck Reaction. J. Am. Chem. Soc. 2009132, 79-81.
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235. Ueda, M.; Hartwig, J.F. Iridium-Catalyzed Regio- and Enantioselective Allylic Substitution with Aromatic and Aliphatic Sulfinates. Org. Lett. 200912, 92-94.
TOC

234. Tye, J.W.; Hartwig, J.F.  Computational Studies on the Relative Rates for Migratory Insertions of Alkenes into Square-Planar Rhodium–Methyl, –Amide, and –Hydroxide Complexes. J. Am. Chem.  Soc.  2009131, 14703.
TOC

233.  Liskey, C.W., Wei, C.S., Pahls, D.R., Hartwig J.F. Pronounced Effects of Substituents on the Iridium-Catalyzed Borylation of Aryl C–H Bonds. Chem. Commun. 20090, 5603-5605.

232. Stanley, L.M.; Hartwig, J.F. Iridium-Catalyzed Regio- and Enantioselective N-Allylation of Indoles. Angew. Chem. Int. Ed.  200948, 7841.

231. Pouy, M.J; Stanley, L.M.; Hartwig, J.F. Enantioselective, Iridium-Catalyzed Monoallylation of Ammonia.. J. Am. Chem. Soc. 2009131, 11312–11313.
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230. Vo, G.D.; Hartwig, J.F. Palladium-Catalyzed Coupling of Ammonia with Aryl Chlorides, Bromides, Iodides, and Sulfonates: A General Method for the Preparation of Primary Arylamines. J. Am. Chem. Soc. 2009131, 11049-11061.
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229. Weix, D.J.; Markovic, D.; Ueda, M.; Hartwig, J.F. Direct, Intermolecular, Enantioselective, Iridium-Catalyzed Allylation of Carbamates to Form Carbamate-Protected, Branched Allylic Amines.. Org. Lett. 200911, 2944–2947.
TOC

228. Stanley, L. M.; Hartwig, J. F.  Regio- and Enantioselective N-Allylations of Imidazole, Benzimidazole, and Purine Heterocycles Catalyzed by Single-Component Metallacyclic Iridium Complexes. J. Am. Chem. Soc. 2009131, 8971-8983.
TOC

227. Alvaro, E.; Hartwig, J.F.  Resting State and Elementary Steps of the Coupling of Aryl Halides with Thiols Catalyzed by Alkylbisphosphine Complexes of Palladium. J. Am. Chem. Soc. 2009131, 7858–7868.
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226. Barrios-Landeros, F.; Carrow, B.P.; Hartwig, J.F Effect of Ligand Steric Properties and Halide Identity on the Mechanism for Oxidative Addition of Haloarenes to Trialkylphosphine Pd(0) Complexes. J. Am. Chem. Soc. 2009131, 8141-8154.
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225. Madrahimov, S.T.; Markovic, D.; Hartwig, J.F. The Allyl Intermediate in Regioselective and Enantioselective Iridium-Catalyzed Asymmetric Allylic Substitution Reaction. J. Am. Chem. Soc. 2009131, 7228-7229.
TOC

224. Fernandez-Rodríguez, M.A.; Hartwig, J.F. A General, Efficient, and Functional-Group-Tolerant Catalyst System for the Palladium-Catalyzed Thioetherification of Aryl Bromides and Iodides. J. Org. Chem. 200974, 1663-1672.
TOC

223. Zhou, J.; Hartwig, J.F. Iridium-Catalyzed H/D Exchange at Vinyl Groups without Olefin Isomerization. Angew. Chem. Int. Ed. 200847, 5783-5787.
TOC

222. Hartwig, J.F. Evolution of a Fourth Generation Catalyst for the Amination and Thioetherification of Aryl Halides. Acc. Chem. Res. 200841, 1534-1544.
TOC

221. Hartwig, J.F. Carbon–Heteroatom Bond Formation Catalysed by Organometallic Complexes. Nature 2008455, 314-322.

220. Boebel, T.A.; Hartwig, J.F. Conversion of 1,3-Disubstituted Arenes to Chiral α,α-Diaryl Methylammonium Chlorides Using Arene Borylation. Tetrahedron 200864, 6824-6830.

219. Boebel, T.A.; Hartwig, J.F. Iridium-Catalyzed Preparation of Silylboranes by Silane Borylation and Their Use in the Catalytic Borylation of Arenes. Organometallics 200827, 6013-6019.
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218. Herzon, S.B.; Hartwig, J.F. Hydroaminoalkylation of Unactivated Olefins with Dialkylamines. J. Am. Chem. Soc. 2008130, 14940–14941.
TOC

217. Alexanian, E.J.; Hartwig, J.F. Mechanistic Study of β-Hydrogen Elimination from Organoplatinum(II) Enolate Complexes. J. Am. Chem. Soc. 2008130, 15627-15635.
TOC

216. Ogata, T.; Hartwig, J.F. Palladium-Catalyzed Amination of Aryl and Heteroaryl Tosylates at Room Temperature. J. Am. Chem. Soc. (Communication) 2008130, 13848-13849.
TOC

215.  Zhou, J. and J.F. Hartwig Intermolecular, Catalytic Asymmetric Hydroamination of Bicyclic Alkenes and Dienes in High Yield and Enantioselectivity.. J. Am. Chem. Soc. 2008130, 12220-12221.
TOC

214. Zhao, P. and J.F. Hartwig Insertions of Ketones and Nitriles into Organorhodium(I) Complexes and b-Hydrocarbyl Eliminations from Rhodium(I) Alkoxo and Iminyl Complexes.. Organometallics 200827, 4749-4757.
TOC

213. Shen, Q. and J.F. Hartwig [(CyPF-tBu)PdCl2]: An Air-Stable, One-Component, Highly Efficient Catalyst for Amination of Heteroaryl and Aryl Halides.. Org. Lett. 200818, 4109-4112.
TOC

212. Tye, J.W., Weng, Z., Johns, A. M., Incarvito, C. D., and J. F. Hartwig Copper Complexes of Anionic Nitrogen Ligands in the Amidation and Imidation of Aryl Halides.. J. Am. Chem. Soc. 2008130, 9971-9983.
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211.  Liao, X., Weng, Z., and J. F. Hartwig Enantioselective-Arylation of Ketones with Aryl Triflates Catalyzed by Difluorphos Complexes of Palladium and Nickel. J. Am. Chem. Soc. 2008130, 195-200.
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210.  Liu, Z., and J.F. Hartwig Mild, Rhodium-Catalyzed Intramolecular Hydroamination of Unactivated Terminal and Internal Olefins with Primary and Secondary Amines.. J. Am. Chem. Soc. 2008130, 1570-1571.
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209.  Ueno, S., and J.F. Hartwig Direct, Iridium-Catalyzed Asymmetric Allylic Etherification with Aliphatic Alcohols.. Angew. Chem. Int. Ed. 200847, 1928-1931.
TOC

208.  Vo, G.D., and J.F. Hartwig Palladium-Catalyzed α-Arylation of Aldehydes with Bromo- and Chloroarenes Catalyzed by [Pd(allyl)Cl]2 and DPPF or Q-phos.. Angew. Chem. Int. Ed. 200847, 2127-2130.
TOC

207.  Shen, Q., Ogata, T., and J.F. Hartwig Highly Reactive, General and Long-Lived Catalysts for Palladium-Catalyzed Amination of Heteroaryl and Aryl Chlorides, Bromides and Iodides: Scope and Structure-Activity Relationships.. J. Am. Chem. Soc. 2008130, 6586-6596.
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206.  Barrios-Landeros, F., Carrow, B.P., and J.F. Hartwig Autocatalytic Oxidative Addition of PhBr to Pd(PtBu3)2 via Pd(PtBu3)2(H)(Br).. J. Am. Chem. Soc. 2008130, 5842-5843.
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205.  Hagedorn, K.V., Varnavski, O., Hartwig, J.F; Goodson III, T. Exciton Trapping in an Organic Dendrimer Possessing No Energy Gradient.. J. Phys. Chem. C. 2008112, 2235-2238.
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204.  Hama, T.; Hartwig, J.F. Palladium-Catalyzed a-Arylation of Esters with Chloroarenes.. Org. Lett. 200810, 1549-1552.
TOC

203.  Hama, T., and J.F. Hartwig a-Arylation of Esters Catalyzed by the Pd(I) Dimer {[P(t-Bu)3]PdBr}2.. Org. Lett. 200810, 1545-1548.
TOC

202.  Boebel, T.A. and J.F. Hartwig Silyl-Directed, Iridium-Catalyzed ortho-Borylation of Arenes. A One-Pot ortho-Borylation of Phenols, Arylamines, and Alkylarenes.. J. Am. Chem. Soc. 2008130, 7534-7535.
TOC

201. Hartwig, J. F. Design and Serendipity in the Discovery and Development of Homogeneous Catalysts for Organic Synthesis. In Catalysis of Organic Reactions: Twenty-Second Conference; Prunier, M. L., Ed.; CRC Press: Boca Raton, 2008; pp 15–21.

200.  Murphy, J.M., Liao, X., and J. F. Hartwig Meta Halogenation of 1,3-Disubstituted Arenes via Iridium-Catalyzed Arene Borylation.. J. Am. Chem. Soc. 2007129, 15434-15435.
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199.  Stambuli, J.P., Weng, Z., Incarvito, C.D., and J. F. Hartwig Reductive Elimination of Ether from T-Shaped, Monomeric Arylpalladium Alkoxides.. Angew. Chem., Int. Ed. 200746, 7674-7677.
TOC

198.  Johns, A.M., Liu, Z., and J. F. Hartwig Primary tert- and sec-Allylamines via Palladium-Catalyzed Hydroamination and Allylic Substitution with Hydrazine and Hydroxylamine Derivatives.. Angew. Chem., Int. Ed. 200746, 7259-7261.
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197.  Markovic, D. and J. F. Hartwig Resting State and Kinetic Studies on the Asymmetric Allylic Substitutions Catalyzed by Iridium-Phosphoramidite Complexes.. J. Am. Chem. Soc. 2007129, 11680-11681.
TOC

196.  Pouy, M. J., Leitner, A., Weix, D. J., Ueno, S. and J. F. Hartwig Enantioselective Iridium-Catalyzed Allylic Amination of Ammonia and Convenient Ammonia Surrogates. Org. Lett. 20079, 3949-3952.
TOC

195.  Shen, Q. and J. F. Hartwig Lewis Acid Acceleration of C-N Bond-Forming Reductive Elimination from Heteroarylpalladium Complexes and Catalytic Amidation of Heteroaryl Bromides. J. Am. Chem. Soc. 2007129, 7734-7735.
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194.  Weix, D. J. and J. F. Hartwig Regioselective and Enantioselective Iridium-Catalyzed Allylation of Enamines. J. Am. Chem. Soc. 2007129, 7720-7721.
TOC

193.  Yamashita, Y., Gopalarathnam, A., and J. F. Hartwig Iridium-Catalyzed, Asymmetric Amination of Allylic Alcohols Activated by Lewis Acids. J. Am. Chem. Soc. 2007129, 7508-7509.
TOC

192.  Herzon, S. B., and J. F. Hartwig Direct, Catalytic Hydroaminoalkylation of Unactivated Olefins with N-Alkyl Arylamines. J. Am. Chem. Soc. 2007129, 6690-6691.
TOC

191.  Hartwig, J. F. Electronic Effects on Reductive Elimination To Form Carbon-Carbon and Carbon-Heteroatom Bonds from Palladium(II) Complexes. Inorg. Chem 200746, 1936-1947.
TOC

190.  Tzschucke, C. C., Murphy, J. M., and J. F. Hartwig Arenes to Anilines and Aryl Ethers by Sequential Iridium-Catalyzed Borylation and Copper-Catalyzed Coupling. Org. Lett. 20079, 761-764.
TOC

189.  Murphy, J. M., Tzschucke, C. C., and J. F. Hartwig One-Pot Synthesis of Arylboronic Acids and Aryl Trifluoroborates by Ir-Catalyzed Borylation of Arenes. Org. Lett. 20079, 757-760.
TOC

188.  Zhao, P., Incarvito, C. D. and J. F. Hartwig Directly Observed Transmetalation from Boron to Rhodium. b-Aryl Elimination from Rh(I) Arylboronates and Diarylborinates. J. Am. Chem. Soc 2007129, 1876-1877.
TOC

187.  Shekhar, S., and J. F. Hartwig Effects of Bases and Halides on the Amination of Chloroarenes Catalyzed by Pd[P(tBu3)]2. Organometallics 200726, 340-351.
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186. Hartwig, J. F.; Shekhar, S.; Shen, Q.; Barrios-landeros, F. Synthesis of Anilines. In The Chemistry of Anilines; Rappoport, Z., Ed.; Wiley-Interscience: New York, 2007; pp 455-536.

185. Hartwig, J. F. Palladium-Catalyzed Amination of Aryl Halides and Sulfonates. In Modern Amination Methods; Ricci, A., Ed.; Wiley-VCH: Weinheim, 2007; pp 195-262.

184.  Johns, A. M, Tye, J. W., and J. F. Hartwig Relative Rates for the Aminations of h3-Allyl and h3-Benzyl Complexes of Palladium. J. Am. Chem. Soc. 2006128, 16010-16011.
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183.  Takemiya, A., and J. F. Hartwig Palladium-Catalyzed Synthesis of Aryl Ketones by Coupling of Aryl Bromides with an Acyl Anion Equivalent. J. Am. Chem. Soc. 2006128, 14800-14801.
TOC

182.  Fernandez-Rodríguez, M. A., Shen, Q., and J. F. Hartwig Highly Efficient and Functional-Group-Tolerant Catalysts for the Palladium-Catalyzed Coupling of Aryl Chlorides with Thiols. Chem.--Eur. J. 200612, 7782-7796.
TOC

181.  Murphy, J. M., Lawrence, J. D., Kawamura, K., Incarvito, C., and J. F. Hartwig Ruthenium-Catalyzed Regiospecific Borylation of Methyl C-H Bonds. J. Am. Chem. Soc. 2006128, 13684-13685.
TOC

180.  Rosenfeld, D. C., Shekhar, S., Takemiya, A., Utsunomiya, M., and J. F. Hartwig Hydroamination and Hydroalkoxylation Catalyzed by Triflic Acid. Parallels to Reactions Initiated with Metal Triflates. Org. Lett. 20068, 4179-4182.
TOC

179.  Shekhar, S., Trantow, B., Leitner, A., and J. F. Hartwig Sequential Catalytic Isomerization and Allylic Substitution. Conversion of Racemic Branched Allylic Carbonates to Enantioenriched Allylic Substitution Products. J. Am. Chem. Soc. 2006128, 11770-11771.
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178.  Su, W.; Raders, S.; Verkade, J.G.; Liao, X; Hartwig, J.F. Palladium-Catalyzed alpha-Arylation of Trimethylsilyl Enol Ethers with Aryl Bromides and Chlorides. A Synergistic Effect of Two Metal Fluorides as Additives. Angew. Chem. 200645, 5852-5855.
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177.  Shen, Q., and J. F. Hartwig Palladium-Catalyzed Coupling of Ammonia and Lithium Amide with Aryl Halides. J. Am. Chem. Soc. 2006128, 10028-10029.
TOC

176.  Zhao, P., Incarvito, C.D., and J. F. Hartwig Carbon-Oxygen Bond Formation between a Terminal Alkoxo Ligand and a Coordinated Olefin. Evidence for Olefin Insertion into a Rhodium-Alkoxide. J. Am. Chem. Soc. 2006128, 9642-9643.
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175.  Fujita, K.I., Yamashita, M, Puschmann, F., Alvarez-Falcon, M.M., Incarvito, C.D., and J. F. Hartwig Organometallic Chemistry from Amidate Complexes. Reductive elimination of N-Aryl Amidates from Palladium(II). J. Am. Chem. Soc. 2006128, 9044-9045.
TOC

174.  J.F. Hartwig Discovery and Understanding of Transition Metal-Catalyzed Aromatic Substitution Reactions. Synlett 20060, 1283-1294.

173.  Sakai, N., Ridder, A., J. F. Hartwig Tropene Derivatives by Sequential Intermolecular and Transannular, Intramolecular Palladium-Catalyzed Hydroamination of Cycloheptatriene. J. Am. Chem. Soc. 2006128, 8134-8135.
TOC

172.  Johns, A.M., Sakai, N., Ridder, A., and J. F. Hartwig Direct Measurement of the Thermodynamics of Vinylarene Hydroamination. J. Am. Chem. Soc. 2006128, 9306-9307.
TOC

171.  Takemiya, A., and J.F. Hartwig Rhodium-Catalyzed Intramolecular, Anti-Markovnikov Hydroamination. Synthesis of 3-Arylpiperidines. J. Am. Chem. Soc. 2006128, 6042-6043.
TOC

170.  Hama, T., Culkin, D. A., and J. F. Hartwig Palladium-Catalyzed Intermolecular a-Arylation of Zinc Amide Enolates under Mild Conditions. J. Am. Chem. Soc. 2006128, 4976-4985.
TOC

169.  Johns, A. M., Utsunomiya, M., Incarvito, C. D., and J. F. Hartwig A Highly Active Palladium Catalyst for Intermolecular Hydroamination. Factors that Control Reactivity and Additions of Functionalized Anilines to Dienes and Vinylarenes. J. Am. Chem. Soc. 2006128, 1828-1839.
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168.  Fernández-Rodríguez, M. A., Shen, Q., and J. F. Hartwig A General and Long-Lived Catalyst for the Palladium-Catalyzed Coupling of Aryl Halides with Thiols. J. Am. Chem. Soc. 2006128, 2180-2181.
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167.  Shekhar, S., Ryberg, P., and J. F. Hartwig Oxidative Addition of Phenyl Bromide to Pd(BINAP) vs Pd(BINAP)(amine). Evidence for Addition to Pd(BINAP). Org. Lett. 20068, 851-854.
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166.  Shekhar, S., Ryberg, P., Hartwig, J. F., Mathew, J. S., Blackmond, D. G., Strieter, E. R., and S. L. Buchwald Reevaluation of the Mechanism of the Amination of Aryl Halides Catalyzed by BINAP-Ligated Palladium Complexes. J. Am. Chem. Soc. 2006128, 3584-3591.
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165.  Zhao, P., Incarvito, C. D., and J. F. Hartwig Direct Observation of b-Aryl Eliminations from Rh(I) Alkoxides. J. Am. Chem. Soc. 2006128, 3124-3125.
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164.  Barrios-Landeros, F. and J. F. Hartwig Distinct Mechanisms for the Oxidative Addition of Chloro-, Bromo-, and Iodoarenes to a Bisphosphine Palladium(0) Complex with Hindered Ligands. J. Am. Chem. Soc. 2005127, 6944-6945.
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163.  Bae, C., Hartwig, J. F., Boaen Harris, N. K., Long, R. O., Anderson, K. S., and M. A. Hillmyer Catalytic Hydroxylation of Polypropylenes. J. Am. Chem. Soc. 2005127, 767-776.
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162.  Boller, T. M., Murphy, J. M., Hapke, M., Ishiyama, T., Miyaura, N., and J. F. Hartwig Mechanism of the Mild Functionalization of Arenes by Diboron Reagents Catalyzed by Iridium Complexes. Intermediacy and Chemistry of Bipyridine-Ligated Iridium Trisboryl Complexes. J. Am. Chem. Soc. 2005127, 14263-14278.
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161.  Graening, T. and J. F. Hartwig Iridium-Catalyzed Regio- and Enantioselective Allylation of Ketone Enolates. J. Am. Chem. Soc. 2005127, 17192-17193.
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160.  Hartwig, J. F. Synthetic Chemistry: Recipes for Excess. Nature 2005437, 487-488.

159.  Hartwig, J. F., Cook, K. S., Hapke, M., Incarvito, C. D., Fan, Y., Webster, C. E., and M. B. Hall Rhodium Boryl Complexes in the Catalytic, Terminal Functionalization of Alkanes. J. Am. Chem. Soc. 2005127, 2538-2552.
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158.  Lee, D.-Y. and J. F. Hartwig Zinc Trimethylsilylamide as a Mild Ammonia Equivalent and Base for the Amination of Aryl Halides and Triflates. Org. Lett. 20057, 1169-1172.
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157.  Leitner, A., Shekhar, S., Pouy, M. J., and J. F. Hartwig A Simple Iridium Catalyst with a Single Resolved Stereocenter for Enantioselective Allylic Amination. Catalyst Selection from Mechanistic Analysis. J. Am. Chem. Soc. 2005127, 15506-15514.
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156.  Leitner, A., Shu, C., and J. F. Hartwig Effects of Catalyst Activation and Ligand Steric Properties on the Enantioselective Allylation of Amines and Phenoxides. Org. Lett. 20057, 1093-1096.
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155.  Limmert, M. E., Roy, A. H., and J. F. Hartwig Kumada Coupling of Aryl and Vinyl Tosylates under Mild Conditions. J. Org. Chem. 2005127, 9364-9370.
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154.  Shen, Q., Shekhar, S., Stambuli, J. P., and J. F. Hartwig Highly Reactive, General, and Long-Lived Catalysts for Coupling Heteroaryl and Aryl Chlorides with Primary Nitrogen Nucleophiles.. Angewandte Chemie International Edition 200544, 1371-1375.

153.  Takaya, J. and J. F. Hartwig Mechanistic Studies of Ruthenium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes: Intermediates and Evidence for Catalysis through p-Arene Complexes. J. Am. Chem. Soc. 2005127, 5756-5757.
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152.  Tsukada, N. and J. F. Hartwig Intermolecular and Intramolecular, Platinum-Catalyzed, Acceptorless Dehydrogenative Coupling of Hydrosilanes with Aryl and Aliphatic Methyl C-H Bonds. J. Am. Chem. Soc. 2005127, 5022-5023.
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151.  Wu, L. and J. F. Hartwig Mild Palladium-Catalyzed Selective Monoarylation of Nitriles. J. Am. Chem. Soc. 2005127, 15824-15832.
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150.  Yan, X. Z., Pawlas, J., Goodson, T., III and J. F. Hartwig Polaron Delocalization in Ladder Macromolecular Systems. J. Am. Chem. Soc. 2005127, 9105-9116.
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149.  Zhao, J., Goldman, A. S., and J. F. Hartwig Oxidative Addition of Ammonia to Form a Stable Monomeric Amido Hydride Complex. Science 2005307, 1080-1082.

148.  Zhao, J. and J. F. Hartwig Acceptorless, Neat, Ruthenium-Catalyzed Dehydrogenative Cyclization of Diols to Lactones. Organometallics 200524, 2441-2446.
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147.  Zhao, P., Krug, C., and J. F. Hartwig Transfer of Amido Groups from Isolated Rhodium(I) Amides to Alkenes and Vinylarenes. J. Am. Chem. Soc. 2005127, 12066-12073.
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146.  Zhao, P. and J. F. Hartwig b-Aryl Eliminations from Rh(I) Iminyl Complexes. J. Am. Chem. Soc. 2005127, 11618-11619.
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145.  Cook, K. S., Incarvito, C. D., Webster, C. E., Fan, Y., Hall, M. B. and J. F. Hartwig Rhodium Silyl Boryl Hydride Complexes: Comparison of Bonding and the Rates of Elimination of Borane, Silane, and Dihydrogen. Angewandte Chemie International Edition 200443, 5474-5477.

144.  Culkin, D. A. and J. F. Hartwig Carbon-Carbon Bond-Forming Reductive Elimination from Arylpalladium Complexes Containing Functionalized Alkyl Groups. Influence of Ligand Steric and Electronic Properties on Structure, Stability, and Reactivity. Organometallics 200423, 3398-3416.
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143.  Krug, C. and J. F. Hartwig Imine Insertion into a Late Metal-Carbon Bond To Form a Stable Amido Complex. J. Am. Chem. Soc. 2004126, 2694-2695.
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142.  Krug, C. and J. F. Hartwig Reactions of an Arylrhodium Complex with Aldehydes, Imines, Ketones, and Alkynones. New Classes of Insertion Reactions. Organometallics 200423, 4594-4607.
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141.  Lawrence, J. D., Takahashi, M., Bae, C. and J. F. Hartwig Regiospecific Functionalization of Methyl C-H Bonds of Alkyl Groups in Reagents with Heteroatom Functionality. J. Am. Chem. Soc. 2004126, 15334-15335.
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140.  Leitner, A., Larsen, J., Steffens, C. and J. F. Hartwig Palladium-Catalyzed Addition of Mono- and Dicarbonyl Compounds to Conjugated Dienes. J. Org. Chem. 200469, 7552-7557.
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139.  Leitner, A., Shu, C., and J. F. Hartwig Editing the Stereochemical Elements in an Iridium Catalyst for Enantioselective Allylic Amination. Proc. Nat. Acad. Sci. U.S.A. 2004101, 5830-5833.

138.  Liu, X. and J. F. Hartwig Palladium-Catalyzed a-Arylation of Trimethylsilyl Enolates of Esters and Imides. High Functional Group Tolerance and Stereoselective Synthesis of a-Aryl Carboxylic Acid Derivatives. J. Am. Chem. Soc. 2004126, 5182-5191.
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137.  Roy, A. H. and J. F. Hartwig Oxidative Addition of Aryl Sulfonates to Palladium(0) Complexes of Mono- and Bidentate Phosphines. Mild Addition of Aryl Tosylates and the Effects of Anions on Rate and Mechanism. Organometallics 200423, 194-202.
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136.  Roy, A. H. and J. F. Hartwig Reductive Elimination of Aryl Halides upon Addition of Hindered Alkylphosphines to Dimeric Arylpalladium(II) Halide Complexes. Organometallics 200423, 1533-1541.
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135.  Shekhar, S. and J. F. Hartwig Distinct Electronic Effects on Reductive Eliminations of Symmetrical and Unsymmetrical Bis-Aryl Platinum Complexes.. J. Am. Chem. Soc. 2004126, 13016-13027.
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134.  Shu, C., Leitner, A. and J. F. Hartwig Enantioselective Allylation of Aromatic Amines after In Situ Generation of an Activated Cyclometalated Iridium Catalyst. Angewandte Chemie International Edition 200443, 4797-4800.

133.  Shu, C. and J. F. Hartwig Iridium-Catalyzed Intermolecular Allylic Etherification with Aliphatic Alkoxides: Asymmetric Synthesis of Dihydropyrans and Dihydrofurans. Angewandte Chemie International Edition 200443, 4794-4797.

132.  Stambuli, J. P., Incarvito, C. D., Buhl, M. and J. F. Hartwig Synthesis, Structure, Theoretical Studies, and Ligand Exchange Reactions of Monomeric, T-Shaped Arylpalladium(II) Halide Complexes with an Additional, Weak Agostic Interaction. J. Am. Chem. Soc. 2004126, 1184-1194.
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131.  Utsunomiya, M. and J. F. Hartwig Ruthenium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes. J. Am. Chem. Soc. 2005126, 2702-2703.
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130.  Yamashita, M. and J. F. Hartwig Synthesis, Structure, and Reductive Elimination Chemistry of Three-Coordinate Arylpalladium Amido Complexes. J. Am. Chem. Soc. 2004126, 5344-5345.
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129. Hartwig, J. F. Palladium-Catalyzed Amination of Aryl Halides and Sulfonates. In Modern Arene Chemistry; Astruc, D., Ed.; Wiley-VCH: Weinheim, 2004; pp 107-168.

128.  Anastasi, N. R., Waltz, K. M., Weerakoon, W. L., and J. F. Hartwig A short synthesis of tetraalkoxydiborane(4) reagents. Organometallics 200322, 365-369.
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127.  Culkin, D. A. and J. F. Hartwig Palladium-catalyzed alpha-arylation of carbonyl compounds and nitriles. Accounts of Chemical Research 200336, 234-245.

126.  Hama, T., Liu, X., Culkin, D. A., and J. F. Hartwig Palladium-Catalyzed a-Arylation of Esters and Amides under More Neutral Conditions. J. Am. Chem. Soc. 2003125, 11176-11177.
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125.  Hooper, M. W., Utsunomiya, M., and J. F. Hartwig Scope and mechanism of palladium-catalyzed amination of five-membered heterocyclic halides. J. Org. Chem. 200368, 2861-2873.
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124.  Hooper, M. W. and J. F. Hartwig Understanding the Coupling of Heteroaromatic Substrates: Synthesis, Structures, and Reductive Eliminations of Heteroarylpalladium Amido Complexes. Organometallics 200322, 3394-3403.
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123.  Ishiyama, T., Takagi, J., Yonekawa, Y., Hartwig, J. F., and N. Miyaura Iridium-Catalyzed Direct Borylation of Five-Membered Heteroarenes by Bis(pinacolato)diboron: Regioselective, Stoichiometric, and Room Temperature Reactions. Advanced Synthesis and Catalysis 2003345, 1103-1106.

122.  Ishiyama, T., Nobuta, Y., Hartwig, J. F., and N. Miyaura Room Temperature Borylation of Arenes and Heteroarenes Using Stoichiometric Amounts of Pinacolborane Catalyzed by Iridium Complexes in an Inert Solvent.. Chemical Communications 200323, 2924-2925.

121.  Kanzelberger, M., Zhang, X., Emge, T. J., Goldman, A. S., Zhao, J., Incarvito, C. D., and J. F. Hartwig Distinct Thermodynamics for the Formation and Cleavage of N-H Bonds in Aniline and Ammonia. Directly-Observed Reductive Elimination of Ammonia from an Isolated Amido Hydride Complex. J. Am. Chem. Soc. 2003125, 13644-13645.
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120.  Kiener, C. A., Shu, C., Incarvito, C. D., and J. F. Hartwig Identification of an Activated Catalyst in the Iridium-Catalyzed Allylic Amination and Etherification. Increased Rates, Scope, and Selectivity. J. Am. Chem. Soc. 2003125, 14272 -14273.
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119.  Liu, X. and J. F. Hartwig Palladium-catalyzed a-arylation of azlactones to form quaternary amino acid derivatives.. Organic Letters 20035, 1915-1918.
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118.  Lopez, F., Ohmura, T., and J. F. Hartwig Regio- and Enantioselective Iridium-Catalyzed Intermolecular Allylic Etherification of Achiral Allylic Carbonates with Phenoxides.. J. Am. Chem. Soc. 2003125, 3426-3427.
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117.  Mann, G., Shelby, Q., Roy, A. H., and J. F. Hartwig Electronic and Steric Effects on the Reductive Elimination of Diaryl Ethers from Palladium(II). Organometallics 200322, 2775-2789.
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116.  Roy, A. H. and J. F. Hartwig Directly Observed Reductive Elimination of Aryl Halides from Monomeric Arylpalladium(II) Halide Complexes. J. Am. Chem. Soc. 2003125, 13944-13945.
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115.  Roy, A. H. and J. F. Hartwig Oxidative Addition of Aryl Tosylates to Palladium(0) and Coupling of Unactivated Aryl Tosylates at Room Temperature. J. Am. Chem. Soc. 2003125, 8704-8705.
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114.  Stambuli, J. P. and J. F. Hartwig Recent Advances in the Discovery of Organometallic Catalysts Using High-Throughput Screening Assays. Current Opinion in Chemical Biology 20037, 420-426.

113.  Stauffer, S. R. and J. F. Hartwig Fluorescence Resonance Energy Transfer (FRET) as a High-Throughput Assay for Coupling Reactions. Arylation of Amines as a Case Study.. J. Am. Chem. Soc. 2003125, 6977-6985.
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112.  Utsunomiya, M., Kawatsura, M., and J. F. Hartwig Palladium-Catalyzed Equilibrium Addition of Acidic OH Groups across Dienes. Angewandte Chemie International Edition 200342, 5865-5868.

111.  Utsunomiya, M., Kuwano, R., Kawatsura, M., and J. F. Hartwig Rhodium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes. J. Am. Chem. Soc. 2003125, 5608-5609.
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110.  Utsunomiya, M. and J. F. Hartwig Intermolecular, Markovnikov Hydroamination of Vinylarenes with Alkylamines. J. Am. Chem. Soc. 2003125, 14286-14287.
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109.  Webster, C. E., Fan, Y., Hall, M. B., Kunz, D., and J. F. Hartwig Experimental and Computational Evidence for a Boron-Assisted, Sigma-Bond Metathesis Pathway for Alkane Borylation. J. Am. Chem. Soc. 2003125, 858-859.
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108.  Yamashita, M., Cuevas Vicario, J. V., and J. F. Hartwig Trans Influence on the Rate of Reductive Elimination. Reductive Elimination of Amines from Isomeric Arylpalladium Amides with Unsymmetrical Coordination Spheres. J. Am. Chem. Soc. 2003125, 16347-16360.
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107. Hartwig, J. F.  Metal Complexes as Catalysts for Carbon-heteroatom Cross-coupling Reactions. In Comprehensive Coordination Chemistry II;  Meyer, T. J., Ed.; Pergamon: Oxford, 2003; pp 369-398.

106. Hartwig, J. F. Palladium-Catalyzed Synthesis of Aryl Ethers and Related Compounds Containing S and Se. In Handbook of Organopalladium Chemistry for Organic Synthesis; Negishi, E. I., Ed.; Wiley-Interscience: New York, 2003; pp 1097-1106.

105. Hartwig, J. F. Palladium-Catalyzed Amination of Aryl Halides and Related Reactions. In Handbook of Organopalladium Chemistry for Organic Synthesis; Negishi, E.I., Ed.; Wiley-Interscience: New York, 2003; pp 1051-1096.

104.  Alcazar-Roman, L. M. and J. F. Hartwig Mechanistic studies on oxidative addition of aryl halides and triflates to Pd(BINAP)2 and structural characterization of the product from aryl triflate addition in the presence of amine. Organometallics 200221, 491-502.
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103.  Beare, N. A. and J. F. Hartwig Palladium-catalyzed arylation of malonates and cyanoesters using sterically hindered trialkyl- and ferrocenyldialkylphosphine ligands. J. Org. Chem. 200267, 541-555.
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102.  Culkin, D. A. and J. F. Hartwig Synthesis, characterization, and reactivity of arylpalladium cyanoalkyl complexes: Selection of catalysts for the alpha-arylation of nitriles. J. Am. Chem. Soc. 2002124, 9330-9331.
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101.  Hartwig, J. F. Raising the bar for the "Perfect reaction". Science 2002297, 1653-1654.

100.  Ishiyama, T., Takagi, J., Hartwig, J. F., and N. Miyaura A stoichiometric aromatic C-H borylation catalyzed by iridium(I)/2,2 '-bipyridine complexes at room temperature. Angewandte Chemie-International Edition 200241, 3056-3058.

99.  Ishiyama, T., Takagi, J., Ishida, K., Miyaura, N., Anasrasi, N. R., and J. F. Hartwig Mild iridium-catalyzed borylation of arenes. High turnover numbers, room temperature reactions, and isolation of a potential intermediate. J. Am. Chem. Soc. 2002124, 390-391.
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98.  Jorgensen, M., Lee, S., Liu, X., Wolkowski, J. P., and J. F. Hartwig Efficient synthesis of a-aryl esters by room-temperature palladium-catalyzed coupling of aryl halides with ester enolates. J. Am. Chem. Soc. 2002124, 12557-12565.
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97.  Kataoka, N., Shelby, Q., Stambuli, J. P., and J. F. Hartwig Air stable, sterically hindered ferrocenyl dialkylphosphines for palladium-catalyzed C-C, C-N, and C-O bond-forming cross-couplings. J. Org. Chem. 200267, 5553-5566.
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96.  Kondo, Y., Garcia-Cuadrado, D., Hartwig, J. F., Boaen, N. K., Wagner, N. L. and A. M. Hillmyer Rhodium-catalyzed, regiospecific functionalization of polyolefins in the melt. J. Am. Chem. Soc. 2002124, 1164-1165.
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95.  Krug, C. and J. F. Hartwig Direct observation of aldehyde insertion into rhodium-aryl and -alkoxide complexes. J. Am. Chem. Soc. 2002124, 1674-1679.
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94.  Kuwano, R., Utsunomiya, M., and J. F. Hartwig Aqueous hydroxide as a base for palladium-catalyzed amination of aryl chlorides and bromides. J. Org. Chem. 200267, 6479-6486.
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93.  Nettekoven, U. and J. F. Hartwig A new pathway for hydroamination. Mechanism of palladium-catalyzed addition of anilines to vinylarenes. J. Am. Chem. Soc. 2002124, 1166-1167.
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92.  Ohmura, T. and J. F. Hartwig Regio- and enantioselective allylic amination of achiral allylic esters catalyzed by an iridium-phosphoramidite complex. J. Am. Chem. Soc. 2002124, 15164-15165.
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91.  Pawlas, J., Nakao, Y., Kawatsura, M., J. F. Hartwig A general nickel-catalyzed hydroamination of 1,3-dienes by alkylamines: Catalyst selection, scope, and mechanism. J. Am. Chem. Soc. 2002124, 3669-3679.
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90.  Ranasinghe, M. I., Varnavski, O. P., Pawlas, J., Hauck, S. I., Louie, J., Hartwig, J. F., and T. Goodson III Femtosecond excitation energy transport in triarylamine dendrimers. J. Am. Chem. Soc. 2002124, 6520-6521.
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89.  Schlummer, B. and J. F. Hartwig Bronsted acid-catalyzed intramolecular hydroamination of protected alkenylamines. Synthesis of pyrrolidines and piperidines. Organic Letters 20024, 1471-1474.
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88.  Stambuli, J. P., Kuwano, R., and J. F. Hartwig Unparalleled rates for the activation of aryl chlorides and bromides: Coupling with amines and boronic acids in minutes at room temperature. Angewandte Chemie-International Edition 200241, 4746-4748.

87.  Stambuli, J. P., Buhl, M., and J. F. Hartwig Synthesis, characterization, and reactivity of monomeric, arylpalladium halide complexes with a hindered phosphine as the only dative ligand. J. Am. Chem. Soc. 2002124, 9346-9347.
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86.  Takagi, J., Sato, K., Hartwig, J. F., Ishiyama, T., and N. Miyaura Iridium-catalyzed C-H coupling reaction of heteroaromatic compounds with bis(pinacolato)diboron: regioselective synthesis of heteroarylboronates. Tetrahedron Letters 200243, 5649-5651.

85.  Wolkowski, J. P. and J. F. Hartwig Generation of Reactivity from Typically Stable Ligands: C-C Bond-Forming Reductive Elimination from Aryl Palladium(II) Complexes of Malonate Anions. Angewandte Chemie-International Edition 2002114, 4465-4467.

84.  Alcazar-Roman, L. M. and J. F. Hartwig Mechanism of aryl chloride amination: Base-induced oxidative addition. J. Am. Chem. Soc. 2001123, 12905-12906.

83.  Chae, H. K., Eddaoudi, M., Kim, J., Hauck, S. I., Hartwig, J. F., O'Keeffe, M., and O. M. Yaghi Tertiary building units: Synthesis, structure, and porosity of a metal-organic dendrimer framework (MODF-1). J. Am. Chem. Soc. 2001123, 11482-11483.

82.  Culkin, D. A. and J. F. Hartwig C-C bond-forming reductive elimination of ketones, esters, and amides from isolated arylpalladium(II) enolates. J. Am. Chem. Soc. 2001123, 5816-5817.

81. Hartwig, J. F. Taking It Personally. Chem. Eng. News 200179, 248.

80.  Kawamura, K. and J. F. Hartwig Isolated Ir(V) boryl complexes and their reactions with hydrocarbons. J. Am. Chem. Soc. 2001123, 8422-8423.

79.  Kawatsura, M. and J. F. Hartwig Transition metal-catalyzed addition of amines to acrylic acid derivatives. A high-throughput method for evaluating hydroamination of primary and secondary alkylamines. Organometallics 200120, 1960-1964.
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78.  Lee, S., Beare, N. A., and J. F. Hartwig Palladium-catalyzed alpha-arylation of esters and protected amino acids. J. Am. Chem. Soc. 2001123, 8410-8411.

77.  Lee, S., M. Jorgensen, and J. F. Hartwig Palladium-catalyzed synthesis of arylamines from aryl halides and lithium bis(trimethylsilyl)amide as an ammonia equivalent. Organic Letters 20013, 2729-2732.
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76.  Lee, S. and J. F. Hartwig Improved catalysts for the palladium-catalyzed synthesis of oxindoles by amide a-arylation. Rate acceleration, use of aryl chloride substrates, and a new carbene ligand for asymmetric transformations. J. Org. Chem. 200166, 3402-3415.
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75.  Lober, O., Kawatsura, M., and J. F. Hartwig Palladium-catalyzed hydroamination of 1,3-dienes: A colorimetric assay and enantioselective additions. J. Am. Chem. Soc. 2001123, 4366-4367.

74.  Roy, A. H. and J. F. Hartwig Reductive elimination of aryl halides from palladium(II). J. Am. Chem. Soc. 2001123, 1232-1233.

73.  Stambuli, J. P., Stauffer, S. R., Shaughnessy, K. H., and J. F. Hartwig Screening of homogeneous catalysts by fluorescence resonance energy transfer. Identification of catalysts for room-temperature Heck reactions. J. Am. Chem. Soc. 2001123, 2677-2678.

72.  Stauffer, S. R., Beare, N .A., Stambuli, J. P., and J. F. Hartwig Palladium-catalyzed arylation of ethyl cyanoacetate. Fluorescence resonance energy transfer as a tool for reaction discovery. J. Am. Chem. Soc. 2001123, 4641-4642.

71.  Zhao, J., Hesslink, H., and J. F. Hartwig Mechanism of b-hydrogen elimination from square planar iridium(I) alkoxide complexes with labile dative ligands. J. Am. Chem. Soc. 2001123, 7220-7227.

70. Shelby, Q.; Kataoka, N.; Mann, G.; Hartwig, J.F. Unusual in situ Ligand Modification to Generate a Catalyst for Room Temperature Aromatic C-O Bond Formation. J. Am. Chem. Soc. 2000122, 10718-10719.

69.  Alcazar-Roman, L. M., Hartwig, J. F., Rheingold, A. L., Liable-Sands, L. M., and I. A. Guzei Mechanistic studies of the palladium-catalyzed amination of aryl halides and the oxidative addition of aryl bromides to Pd(BINAP)2 and Pd(DPPF)2: An unusual case of zero-order kinetic behavior and product inhibition. J. Am. Chem. Soc. 2000122, 4618-4630.

68.  Chen, H. Y., Schlecht, S., Semple, T. C., and J. F. Hartwig Thermal, catalytic, regiospecific functionalization of alkanes. Science 2000287, 1995-1997.

67.  Hartwig, J. F. and C. N. Muhoro Mechanistic studies of titanocene-catalyzed alkene and alkyne hydroboration: Borane complexes as catalytic intermediates. Organometallics 200019, 30-38.
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66.  Ishiyama, T. and J. Hartwig A Heck-type reaction involving carbon-heteroatom double bonds. Rhodium(I)-catalyzed coupling of aryl halides with N-pyrazyl aldimines. J. Am. Chem. Soc. 2000122, 12043-12044.

65.  Kawatsura, M. and J. F. Hartwig Palladium-catalyzed intermolecular hydroamination of vinylarenes using arylamines. J. Am. Chem. Soc. 2000122, 9546-9547.

64.  Schlecht, S. and J. F. Hartwig s-borane complexes of manganese and rhenium. J. Am. Chem. Soc. 2000122, 9435-9443.

63.  Stauffer, S. R., Lee, S., Stambuli, J. P., Hauck, S. I., and J. F. Hartwig High turnover number and rapid, room-temperature amination of chloroarenes using saturated carbene ligands. Organic Letters 20002, 1423-1426.
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62.  Waltz, K. M. and J. F. Hartwig Functionalization of alkanes by isolated transition metal boryl complexes. J. Am. Chem. Soc. 2000122, 11358-11369.

61.  Chen, H. Y. and J. F. Hartwig Catalytic, regiospecific end-functionalization of alkanes: Rhenium-catalyzed borylation under photochemical conditions. Angewandte Chemie-International Edition 199938, 3391-3393.

60.  Goodson, F. E., Hauck, S. I., and J. F. Hartwig Palladium-catalyzed synthesis of pure, regiodefined polymeric triarylamines. J. Am. Chem. Soc. 1999121, 7527-7539.

59. Hartwig, J. F. Approaches to catalyst discovery. New carbon–heteroatom and carbon–carbon bond formation. Pure Appl. Chem. 199971, 1417-1423.

58.  Hartwig, J. F., Kawatsura, M., Hauck, S. I., Shaughnessy, K. H., and L. M. Alcazar-Roman Room-temperature palladium-catalyzed amination of aryl bromides and chlorides and extended scope of aromatic C-N bond formation with a commercial ligand. J. Org. Chem. 199964, 5575-5580.
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57.  Hauck, S. I., Lakshmi, K. V. and J. F. Hartwig Tetraazacyclophanes by palladium-catalyzed aromatic amination. Geometrically defined, stable, high-spin diradicals. Organic Letters 19991, 2057-2060.
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56.  Kawatsura, M. and J. F. Hartwig Simple, highly active palladium catalysts for ketone and malonate arylation: Dissecting the importance of chelation and steric hindrance. J. Am. Chem. Soc. 1999121, 1473-1478.

55.  Mann, G., Incarvito, C. D., Rheingold, A. L., and J. F. Hartwig Palladium-catalyzed C-O coupling involving unactivated aryl halides. Sterically induced reductive elimination to form the C-O bond in diaryl ethers. J. Am. Chem. Soc. 1999121, 3224-3225.

54.  Muhoro, C. N., He, X. M., and J. F. Hartwig Titanocene borane sigma-complexes. J. Am. Chem. Soc. 1999121, 5033-5046.

53.  Shaughnessy, K. H., Kim, P., and J. F. Hartwig A fluorescence-based assay for high-throughput screening of coupling reactions. Application to Heck chemistry. J. Am. Chem. Soc. 1999121, 2123-2132.

52.  Waltz, K. M., Muhoro, C. N., and J. F. Hartwig C-H activation and functionalization of unsaturated hydrocarbons by transition-metal boryl complexes. Organometallics 199918, 3383-3393.
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51.  Driver, M. S. and J. F. Hartwig Oxidative addition and reductive elimination reactions of trans-[Ir(PPh3)2(CO)(NC4H4)] and trans,cis-[Ir(PPh3)2(H)2(CO)(NC4H4)] including N-H bond-forming reductive elimination of pyrrole. Organometallics 199817, 1134-1143.

50.  Goodson, F. E. and J. F. Hartwig Regiodefined poly(N-arylaniline)s and donor-acceptor copolymers via palladium-mediated amination chemistry. Macromolecules 199831, 1700-1703.

49.  Hamann, B. C. and J. F. Hartwig Sterically hindered chelating alkyl phosphines provide large rate accelerations in palladium-catalyzed amination of aryl iodides, bromides, and chlorides, and the first amination of aryl tosylates. J. Am. Chem. Soc. 1998120, 12706-12706.

48.  Hamann, B. C. and J. F. Hartwig Sterically hindered chelating alkyl phosphines provide large rate accelerations in palladium-catalyzed amination of aryl iodides, bromides, and chlorides, and the first amination of aryl tosylates. J. Am. Chem. Soc. 1998120, 7369-7370.

47.  Hamann, B. C. and J. F. Hartwig Systematic variation of bidentate ligands used in aryl halide amination. Unexpected effects of steric, electronic, and geometric perturbations. J. Am. Chem. Soc. 1998120, 3694-3703.

46.  Hartwig, J. F. Carbon-heteroatom bond-forming reductive eliminations of amines, ethers, and sulfides. Accounts of Chemical Research 199831, 852-860.

45.  Hartwig, J. F. Transition metal catalyzed synthesis of arylamines and aryl ethers from aryl halides and triflates: Scope and mechanism. Angewandte Chemie-International Edition 199837, 2047-2067.

44.  Hartwig, J. F. Synthesis, structure, and reactivity of a palladium hydrazonato complex: A new type of reductive elimination reaction to form C-N bonds and catalytic arylation of benzophenone hydrazone. Angewandte Chemie-International Edition 199837, 2090-2093.

43.  Louie, J. and J. F. Hartwig The largest discrete oligo(m-aniline). An exponential growth strategy using palladium-catalyzed amination of aryl sulfonates. Macromolecules 199831, 6737-6739.

42.  Mann, G., Baranano, D., Hartwig, J. F., Rheingold, A. L., and I. A. Guzei Carbon-sulfur bond-forming reductive elimination involving sp-, sp2-, and sp3-hybridized carbon. Mechanism, steric effects, and electronic effects on sulfide formation. J. Am. Chem. Soc. 1998120, 9205-9219.

41.  Mann, G., Hartwig, J. F., Driver, M. S., and C. Fernandez-Rivas Palladium-catalyzed C-N(sp2) bond formation: N-arylation of aromatic and unsaturated nitrogen and the reductive elimination chemistry of palladium azolyl and methyleneamido complexes. J. Am. Chem. Soc. 1998120, 827-828.

40.  Shaughnessy, K. H., Hamann, B. C., and J. F. Hartwig Palladium-catalyzed inter- and intramolecular alpha-arylation of amides. Application of intramolecular amide arylation to the synthesis of oxindoles. J. Org. Chem. 199863, 6546-6553.
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39. Hartwig, J. F.; Waltz, K. M.; Muhoro, C. N. Hydrocarbon Functionalization by Late Metal Boryls and Chemistry of Titanocene-Bound Catecholborane. In Advances in Boron Chemistry; W. Siebert, Ed.; The Royal Society of Chemistry: Cambridge, 1997; pp 373-380.

38. Baranano, D.; Mann, G., and Hartwig, J. F.  Nickel and palladium-catalyzed cross-couplings that form carbon-heteroatom and carbon-element bonds. Current Organic Chemistry 19971, 287-305.

37.  Driver, M. S. and J. F. Hartwig Energetics and mechanism of alkylamine N-H bond cleavage by palladium hydroxides: N-H activation by unusual acid-base chemistry. Organometallics 199716, 5706-5715.

36.  Driver, M. S. and J. F. Hartwig Carbon-nitrogen-bond-forming reductive elimination of arylamines from palladium(II) phosphine complexes. J. Am. Chem. Soc. 1997119, 8232-8245.

35.  Hamann, B. C. and J. F. Hartwig Palladium-catalyzed direct alpha-arylation of ketones. Rate acceleration by sterically hindered chelating ligands and reductive elimination from a transition metal enolate complex. J. Am. Chem. Soc. 1997119, 12382-12383.

34. Hartwig, J. F. Palladium-Catalyzed Amination of Aryl Halides: Mechanism and Rational Catalyst Design. Synlett 19971997, 329-340.

33.  Louie, J., Hartwig, J. F., and A. J. Fry Discrete high molecular weight triarylamine dendrimers prepared by palladium-catalyzed amination. J. Am. Chem. Soc. 1997119, 11695-11696.

32.  Louie, J., Driver, M. S., Hamann, B. C., and J. F. Hartwig Palladium-catalyzed amination of aryl triflates and importance of triflate addition rate. J. Org. Chem. 199762, 1268-1273.
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31.  Mann, G. and J. F. Hartwig Palladium-catalyzed formation of diaryl ethers from aryl bromides. Electron poor phosphines enhance reaction yields. Tetrahedron Letters 199738, 8005-8008.

30.  Mann, G. and J. F. Hartwig Nickel- vs palladium-catalyzed synthesis of protected phenols from aryl halides. J. Org. Chem. 199762, 5413-5418.
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29. Muhoro, C. N.; Hartwig, J. F. Synthesis, Structure, and Reactivity of [Cp2Ti(HBcat)(PMe3)]: A Monoborane σ Complex. Angew. Chem., Int. Ed. Engl. 199736, 1510-1512.
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28.  Waltz, K. M. and J. F. Hartwig Selective functionalization of alkanes by transition-metal boryl complexes. Science 1997277, 211-213.

27.  Driver, M. S. and J. F. Hartwig A second-generation catalyst for aryl halide amination: Mixed secondary amines from aryl halides and primary amines catalyzed by (DPPF)PdCl2. J. Am. Chem. Soc. 1996118, 7217-7218.

26.  Driver, M. S. and J. F. Hartwig General N-H activation of primary alkylamines by a late transition-metal complex. J. Am. Chem. Soc. 1996118, 4206-4207.

25.  Hartwig, J. F. and X. M. He Structural and reaction chemistry of tungstenocene boryl complexes. Organometallics 199615, 5350-5358.
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24.  Hartwig, J. F., Muhoro, C. N., He, X., Eisenstein, O., Bosque, R., and F. Maseras Catecholborane bound to titanocene. Unusual coordination of ligand sigma-bonds. J. Am. Chem. Soc. 1996118, 10936-10937.

23.  Hartwig, J. F. Directly-observed b-hydrogen elimination of a late transition metal amido complex and unusual fate of imine byproducts. J. Am. Chem. Soc. 1996118, 7010-7011.

22.  Hartwig, J. F., Richards, S., Baranano, D., and F. Paul Influences on the relative rates for C-N bond-forming reductive elimination and beta-hydrogen elimination of amides. A case study on the origins of competing reduction in the palladium-catalyzed amination of aryl halides. J. Am. Chem. Soc. 1996118, 3626-3633.

21. Hartwig, J. F.; He, X. Reactivity of Tungstenocene with B-B and B-H Bonds versus C-H Bonds. Angew. Chem., Int. Ed. Engl. 199635, 315-317.
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20.  He, X. M. and J. F. Hartwig True metal-catalyzed hydroboration with titanium. J. Am. Chem. Soc. 1996118, 1696-1702.

19.  He, X. M. and J. F. Hartwig Boryls bound to iron carbonyl. Structure of a rare bis(boryl) complex, synthesis of the first anionic boryl, and reaction chemistry that includes the synthetic equivalent of boryl anion transfer. Organometallics 199615, 400-407.
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18. Louie, J.; Hartwig, J.F A Route to Pdo from PdII Metallacycles in Animation and Cross-Coupling Chemistry. Angew. Chem., Int. Ed. Engl. 199635, 2359-2361.
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17.  Louie, J., F. Paul, and J. F. Hartwig Catalysis with platinum-group alkylamido complexes, the active palladium amide in catalytic aryl halide aminations as deduced from kinetic data and independent generation. Organometallics 199615, 2794-2805.
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16.  Mann, G. and J. F. Hartwig Palladium alkoxides: Potential intermediacy in catalytic amination, reductive elimination of ethers, and catalytic etheration. Comments on alcohol elimination from Ir(III). J. Am. Chem. Soc. 1996118, 13109-13110.

15.  Rablen, P. R. and J. F. Hartwig Accurate borane sequential bond dissociation energies by high-level ab initio computational methods. J. Am. Chem. Soc. 1996118, 4648-4653.

14.  Baranano, D. and J. F. Hartwig Carbon-Heteroatom Bond-Forming Reductive Elimination - Mechanism, Importance of Trapping Reagents, and Unusual Electronic Effects During Formation of Aryl Sulfides. J. Am. Chem. Soc. 1995117, 2937-2938.

13.  Driver, M. S. and J. F. Hartwig A Rare, Low-Valent Alkylamido Complex, a Diphenylamido Complex, and Their Reductive Elimination of Amines by 3-Coordinate Intermediates. J. Am. Chem. Soc. 1995117, 4708-4709.

12.  Paul, F., Patt, J., and J. F. Hartwig Structural Characterization and Simple Synthesis of (Pd[P(O-Tol)3]2), Dimeric Palladium(II) Complexes Obtained by Oxidative Addition of Aryl Bromides, and Corresponding Monometallic Amine Complexes. Organometallics 199514, 3030-3039.

11.  Hartwig, J. F. and F. Paul Oxidative Addition of Aryl Bromide after Dissociation of Phosphine from a 2-Coordinate Palladium(0) Complex, Bis(Tri-O-Tolylphosphine)Palladium(0). J. Am. Chem. Soc. 1995117, 5373-5374.

10.  Louie, J. and J. F. Hartwig Transmetalation Involving Organotin Aryl, Thiolate, and Amide Compounds - an Unusual Type of Dissociative Ligand Substitution-Reaction. J. Am. Chem. Soc. 1995117, 11598-11599.

9.  Louie, J. and J. F. Hartwig Palladium-Catalyzed Synthesis of Arylamines from Aryl Halides - Mechanistic Studies Lead to Coupling in the Absence of Tin Reagents. Tetrahedron Letters 199536, 3609-3612.

8.  Waltz, K.M., He, X., Muhoro, C., and J. F. Hartwig Hydrocarbon Functionalization by Transition-Metal Boryls. J. Am. Chem. Soc. 1995117, 11357-11358.

7.  Hartwig, J. F. and S. R. De Gala A Continuum Resulting from Equilibrium between 2 Structural Extremes in Tungstenocene and Niobocene Boryl and Hydridoborate Complexes - p-Bonding in a d2 Boryl System and the First d0 Boryl Complex. J. Am. Chem. Soc. 1994116, 3661-3662.

6.  Hartwig, J. F., Bhandari, S., and P. R. Rablen Addition of Catecholborane to a Ruthenium-Alkyl - Evidence for Sigma-Bond Metathesis with a Low-Valent, Late Transition-Metal. J. Am. Chem. Soc. 1994116, 1839-1844.

5.  Paul, F., Patt, J., and J. F. Hartwig Palladium-Catalyzed Formation of Carbon-Nitrogen Bonds - Reaction Intermediates and Catalyst Improvements in the Hetero Cross-Coupling of Aryl Halides and Tin Amides. J. Am. Chem. Soc. 1994116, 5969-5970.

4.  Rablen, P. R., Hartwig, J. F., and S. P. Nolan First Transition Metal-Boryl Bond-Energy and Quantitation of Large Differences in Sequential Bond-Dissociation Energies of Boranes. J. Am. Chem. Soc. 1994116, 4121-4122.

3.  Hartwig, J. F. and S. Huber Transition-Metal Boryl Complexes - Structure and Reactivity of CpFe(CO)2Bcat and CpFe(CO)2BPh2. J. Am. Chem. Soc. 1993115, 4908-4909.

2. Burn, M.J.; Fickes, M.G.; Hartwig, J.F.; Hollander, F.J.; Bergman, R.G. Synthesis of Monomeric Ruthenium Hydroxo Complexes (PMe3)4Ru(R)(OH) (R=H, Me) and a Unique Dimeric Ruthenium Hydroxo Water Complex [trans-Ru(H)(OH)(DMPE)2.H2O]2J. Am. Chem. Soc. 1993115, 5875-5876.

1. Hartwig, J.F.; Pil, P.M.; Lippard, S.J. Synthesis and DNA Binding Properties of a Cisplatin Analogue Containing a Tethered Dansyl Group. J. Am. Chem. Soc. 1992114, 8292-8293.